Synthesis and Structure of Di-I/i-acetato(0,0')-ferrocenylmethyliden- 2,4,6-trimethylaniline(N,C)-palladium(II)l
نویسندگان
چکیده
Reaction of Na-,PdCl4 with N-ferrocenylmethylidene-2,4,6-trimethylaniline yields the di meric, chloro-bridged Pd(II) complex [Pd{(C5H 5)FeC5H 3C(H )=N -2 ,4,6-(CH3)3C6H2}Cl]2. The title complex (1 ) is obtained by substitution of the chloro-bridges with acetate. 1 crystallizes in the orthorhombic space group Pbca with the lattice parameters a = 1346.4(4), b = 2876.6(2), c = 2472.8(5) pm and Z = 8. In the dimeric complex each Pd2+ cation exhibits a square-planar coordination by the N atom and an ortho-C atom of the cyclopentadienyl ring of the Schiffbase and two oxygen atoms of two different bridging acetato groups.
منابع مشابه
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